Date: Thu, 29 May 2003 00:09:20 -0400 (EDT) From: "Keith F. Lynch" <kfl at KeithLynch.net> To: WSFA members <WSFAlist at KeithLynch.net> Subject: [WSFA] Re: reference kilogram slowly evaporating Reply-To: WSFA members <WSFAlist at keithlynch.net> ronkean at juno.com wrote: > The kilogram is getting lighter, scientists say, sowing potential > confusion over a range of scientific endeavor. Interesting concept. If the kilogram is *defined* as the mass of that platinum-iridium cylinder, then how can that cylinder ever be said to have changed in mass, even if a prankster were to knock a big chunk out of it? Obviously there's some more natural concept of mass which the official definition unsuccessfully attempts to capture. The metric system's original approach was to define a particular volume (one cubic centimeter) of a particular substance (pure water) at a particular temperature (that at which is is maximally dense, about 4 C or 39 F) as having a specific mass (one gram). They could go back to something like that. (If they choose water again, they'd better specify the isotope ratio, as "pure water" is otherwise ambiguous, with a range of densities.) Another approach to a disaster-proof mass standard is to define it as a specific number of atoms of a specific substance. If that substance is carbon 12, this has the effect of defining Avagodro's number as a particular exact number, in much the same way as the redefinition of the meter twenty years ago had the effect of defining the speed of light as a particular exact number (299,792,458 meters per second, exactly). Another approach would be to define mass in terms of energy instead of (as is currently done) vice versa. But then how to define the unit of energy? Define Planck's constant as a particular exact number, and the energy unit will come from the second, just as the meter does. Alternatively, define Boltzmann's constant as a particular exact number, and the energy unit will come from the temperature unit, which comes from the triple point temperature of pure water. Several other ways of defining an energy unit are possible. One thing we don't want to do is define the gravitational constant as some particular exact number. Since that constant is only known to four place precision, setting up our system of units such that it's an exact number would make everything else measurable only to four place precision. This is a fascinating field, as it really illuminates the fuzzy border between what is true because we've measured it and what is true by definition. Mass isn't just one concept, it's several very similar but subtly different concepts. Similarly with distance, time, and electric charge. There's some weak evidence that the fine structure constant, a dimensionless number which equals the square of the charge of the electron divided by the product of the speed of light and Planck's constant, may have been slightly different in the distant past. If so, it's not clear whether it's meaningful to attribute that difference to a change in the speed of light, a change in Planck's constant, or a change in the charge of an electron, or whether any such choice would be completely arbitrary, no better or worse than any other. Our system of units pretty much forces the speed of light to have been constant. We can also nail down either Planck's constant or the charge of the electron, by defining it as a certain number. But not all three at once. You missed another good Balticon. -- Keith F. Lynch - kfl at keithlynch.net - http://keithlynch.net/ I always welcome replies to my e-mail, postings, and web pages, but unsolicited bulk e-mail (spam) is not acceptable. Please do not send me HTML, "rich text," or attachments, as all such email is discarded unread.